Excitations in Organic Solids (International Series of by Vladimir M. Agranovich, Gerard Czajkowski PDF

By Vladimir M. Agranovich, Gerard Czajkowski

ISBN-10: 0191552917

ISBN-13: 9780191552915

ISBN-10: 0199234418

ISBN-13: 9780199234417

Over the past decade our services in nanotechnology has complex significantly. the potential of incorporating within the related nanostructure various natural and inorganic fabrics has unfolded a promising box of analysis, and has drastically elevated the curiosity within the examine of homes of excitations in natural fabrics. during this e-book not just the basics of Frenkel exciton and polariton idea are defined, but additionally the digital excitations and digital power transfers in quantum wells, quantum wires and quantum dots, at surfaces, at interfaces, in skinny motion pictures, in multilayers, and in microcavities. one of the new themes within the e-book are these dedicated to the optics of hybrid Frenkel-Wannier-Mott excitons in nanostructures, polaritons in natural microcavities together with hybrid organic-inorganic microcavities, new ideas for natural gentle emitting units, the blending of Frenkel and charge-transfer excitons in natural quasi one-dimensional crystals, excitons and polaritons in a single and two-dimensional crystals, floor digital excitations, optical biphonons, and Fermi resonances by means of polaritons. All new phenomena defined within the ebook are illustrated through on hand experimental observations.The booklet could be beneficial for scientists operating within the box of photophysics and photochemistry of natural solids (for instance, natural light-emitting units and sun cells), and for college students who're coming into this box. it's in part according to a ebook via the writer written in 1968 - "Theory of Excitons" - in Russian. but the new booklet contains purely five chapters from this model, all of that have been up to date. the ten new chapters comprise discussions of recent phenomena, their conception and their experimental observations.

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Example text

One of the representations of the point group D3 has dimension two. Thus, if the vector k0 is parallel to the three-fold symmetry axis when the point ˆ k coincides with the point group D3 , a double degeneracy of excitonic group G 0 terms is, in general, possible. There is another reason for degeneracy of excitonic states, being a consequence of the structure of the Schr¨ odinger equation. Indeed, since the Hamiltonian is a self-conjugated operator, wavefunctions Ψ∗k0 μ ( = 1, 2, . . , p), where the star means complex conjugate, as well as wavefunctions Ψk0 μ ( = 1, 2, .

And the crystal factor group. The symmetry group of the molecule contains all symmetry operations, which leave the molecule unchanged. The site groups α contain only those elements of the molecule symmetry, which leave unchanged not only the molecule α, but also the whole crystal. Clearly each site group is a subgroup of the molecule symmetry group. Both are point groups. For explaining the notion of a factor group we notice that any space group contains the subgroup of translations T comprising an infinite set of all parallel displacements which leave the crystal lattice unchanged.

Bnf ϕfn (ξn ), nf 38 EXCITONS IN SECOND QUANTIZATION REPRESENTATION b†nf ϕ∗f n (ξn ), ψˆ† (. . ξn . 9) nf we obtain the transition from operators in the Schr¨ odinger representation into operators in the second-quantization representation. For example, the operator of the total number of crystal molecules can be put into the form b†nf bnf . ˆ . ξn . )dξ = ψˆ† (. . ξn . )ψ(. 10) nf The crystal energy operator without intermolecular interactions can be obtained from the transformation ˆ n (ξn ) → H ˆ0 , H n ψˆ† (.

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Excitations in Organic Solids (International Series of Monographs on Physics) by Vladimir M. Agranovich, Gerard Czajkowski

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